No, Microsoft Outlook 2010 is not going to have size restrictions on what you send. But there are two reasons why this plan will not work.
First, your ISP almost certainly has a limitation on the size of an email that you can send. Movies and full-length videos are huge and ISPs don’t like it when you email files that big. So, they’re probably not going to let you do it.
Second, you’re not going to want to do it that way anyway because what you’re talking about is using email, and that means uploading it (all) to your email provide, and then downloading it (all) to your other machine. Even on a fast internet connection that’ll take a lot of time.
There are better ways.